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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
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Ionic liquid syntheses via click chemistry: expeditious routes toward versatile functional materials
1Department of Chemistry and Physics, Florida Gulf Coast University, Fort Myers, Florida 33965, USA. amirjafari@fgcu.edu.
Chemical Communications (Cambridge, England)
|February 28, 2018
Summary
Click chemistry enables efficient synthesis of functional ionic liquids. This review highlights copper(i)-catalyzed azide-alkyne cycloaddition (CuAAC) and thiol-X reactions for creating tailored soft materials.
Area of Science:
- Materials Science
- Organic Chemistry
- Chemical Synthesis
Background:
- Click chemistry, introduced in 2001, provides a robust platform for forming carbon-heteroatom bonds.
- Key reactions include copper(i)-catalyzed azide-alkyne Huisgen cycloaddition (CuAAC) and thiol-X couplings.
Purpose of the Study:
- To review the application of click chemistry in synthesizing functional ionic liquids.
- To explore challenges, opportunities, and future directions in this field.
Main Methods:
- Focus on CuAAC, thiol-X, and oxime formation reactions.
- Includes discussion of nucleophilic ring-opening reactions.
Main Results:
- Click chemistry facilitates the efficient and robust generation of tailored, task-specific ionic liquids.
- Ionic liquids are an important class of soft materials.
Conclusions:
- Click chemistry offers significant opportunities for developing novel functional ionic liquids.
- The field presents intriguing perspectives for advancing soft materials science.
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