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Updated: Feb 13, 2026

Particles without a Box: Brush-first Synthesis of Photodegradable PEG Star Polymers under Ambient Conditions
Published on: October 10, 2013
Synthesis and Applications of Compartmentalised Molecular Polymer Brushes
Théophile Pelras1,2, Clare S Mahon1,3, Markus Müllner1,2
1Key Centre for Polymers and Colloids, School of Chemistry, The University of Sydney, Sydney, 2006, NSW, Australia.
Abstract:
Polymer science is rapidly advancing towards the precise construction of synthetic macromolecules of formidable complexity. Beyond the impressive advances in control over polymer composition and uniformity enabled by the living polymerisation revolution, the introduction of compartmentalisation within polymer architectures can elevate their functionality beyond that of their constituent parts, thus offering immense potential for the production of tailor-made nanomaterials. In this Minireview, we discuss synthetic routes to complex molecular brushes with discrete chemical compartments and highlight their potential in the development of advanced materials with applications in nanofabrication, optics and functional materials.
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