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Cascade Dehydrogenative Hydroboration for the Synthesis of Azaborabenzofulvenes
Kang Yuan1, Xiang Wang1, Suning Wang1
1Department of Chemistry , Queen's University , Kingston , Ontario K7L 3N6 , Canada.
Abstract:
Tandem dehydrogenative hydroboration has been established to be highly effective in the synthesis of BN isosteres of benzofulvene and derivatives. The scope of this synthetic method is applicable to a variety of substrates. Spectroscopic and computational studies indicate that the new azaborabenzofulvenes have similar electronic properties as their carbonaceous analogues.
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