Fluoroethylene Carbonate Enabling a Robust LiF-rich Solid Electrolyte Interphase to Enhance the Stability of the MoS₂...

As a high-capacity anode for lithium-ion batteries (LIBs), MoS₂ suffers from short lifespan that is due in part to its unstable solid electrolyte interphase (SEI). The cycle life of MoS₂ can be greatly extended by manipulating the SEI with a fluoroethylene carbonate (FEC) additive. The capacity of MoS₂ in the electrolyte with 10 wt % FEC stabilizes at about 770 mAh g^-1 for 200 cycles at 1 A g^-1 , which far surpasses the FEC-free counterpart (ca. 40 mAh g^-1 after 150 cycles). The presence of FEC enables a robust LiF-rich SEI that can effectively inhibit the continual electrolyte decomposition. A full cell with a LiNi_0.5 Co_0.3 Mn_0.2 O₂ cathode also gains improved performance in the FEC-containing electrolyte. These findings reveal the importance of controlling SEI formation on MoS₂ toward promoted lithium storage, opening a new avenue for developing metal sulfides as high-capacity electrodes for LIBs.