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Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
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Characterization of Intermediate Oxidation States in CO2 Activation
Leah G Dodson1, Michael C Thompson2, J Mathias Weber2
1JILA and NIST, University of Colorado, Boulder, Colorado 80309-0440, USA;
Annual Review of Physical Chemistry
|March 1, 2018
Summary
Understanding the redox chemistry of carbon dioxide (CO2) is key. This study explores the intermediate oxidation states of CO2 and related functional units, including ions and ligands.
Area of Science:
- Chemistry
- Inorganic Chemistry
- Physical Chemistry
Background:
- Redox chemistry of carbon dioxide (CO2) activation involves charge state changes.
- Integer formal charges often fail to adequately describe these transformations.
- CO2-derived functional units can exist in intermediate oxidation states.
Purpose of the Study:
- To discuss the properties of CO2 and its derived functional units across various charge states.
- To provide a comprehensive overview of CO2-based species.
- To explore the behavior of CO2 functional groups in complexes.
Main Methods:
- Theoretical analysis of electronic structures.
- Review of existing literature on CO2 and its derivatives.
- Examination of properties of isolated CO2, its ions, and related species.
Main Results:
- Detailed discussion of CO2 and its anionic/cationic forms.
- Characterization of formate, oxalate, and carbonate as key CO2-based ionic species.
- Overview of CO2-based functional groups and ligands in clusters and metal-organic frameworks (MOFs).
Conclusions:
- CO2 redox chemistry is characterized by intermediate oxidation states.
- Understanding these states is crucial for CO2 activation and utilization.
- The study provides a foundational resource for CO2 chemistry research.
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