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Design, Synthesis, and Photochemical Properties of Clickable Caged Compounds
Published on: October 15, 2019
Synthesis and photoluminescence properties of co-polyamides with anthrazoline-containing units in the main chain
Mikhail Ya Goikhman1,2, Irina A Valieva1, Irina V Podeshvo1
1Institute of Macromolecular Compounds of the Russian Academy of Sciences, Saint-Peterburg, Russian Federation.
Abstract:
A series of anthrazoline-containing monomers are synthesized, and eight co-polyamides of different chemical structures, containing 1,9-anthrazoline fragments in the main chain, are obtained and investigated. Photoluminescent, stress-strain, and thermal properties of these polymers are studied. It is shown that polymers with fragments of 4,4'-(pyrido[3,2-g]-quinoline-2,8-diyl)dianiline and 4,4'-(10-methylpyrido[3,2-g]quinoline-2,8-diyl)dianiline possess an intense luminescence in the range 550-650 nm. The performed investigations made it possible to determine the effect of substituents of various natures in the anthrazoline cycle and the position of amide group (meta- and para-configurations) on optical, stress-strain, and thermal properties of copolymers, opening up a prospect for further developments of principles of design of polymers with optimal characteristics.
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