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Updated: Feb 13, 2026

Mesocosm-Scale Constructed Wetland Design for Wastewater Treatment
Published on: May 2, 2025
Biotic phase micropollutant distribution in horizontal sub-surface flow constructed wetlands
Bruce Petrie1, Shawn Rood2, Benjamin D Smith3
1Department of Chemistry, University of Bath, Bath BA2 7AY, UK; Water Innovation & Research Centre (WIRC), University of Bath, Bath BA2 7AY, UK; School of Pharmacy and Life Sciences, Robert Gordon University, Aberdeen AB10 7GJ, UK.
Horizontal sub-surface flow constructed wetlands effectively remove micropollutants. Biodegradation is the primary removal mechanism, though sludge partitioning and plant uptake also play roles in micropollutant removal.
Area of Science:
- Environmental Science
- Environmental Chemistry
- Wastewater Treatment
Background:
- Micropollutants, including pharmaceuticals and personal care products, are increasingly detected in aquatic environments.
- Constructed wetlands are a promising technology for tertiary wastewater treatment.
- Understanding micropollutant fate in constructed wetlands is crucial for effective water management.
Purpose of the Study:
- To investigate the distribution and fate of diverse micropollutants in horizontal sub-surface flow (HSSF) constructed wetlands.
- To assess the removal efficiency and transformation of micropollutants during tertiary wastewater treatment.
- To identify the primary mechanisms responsible for micropollutant removal in HSSF systems.
Main Methods:
- Monitoring of 88 micropollutants in full-scale HSSF steel slag and gravel beds.
- Analysis of micropollutant concentrations in influent, effluent, sludge, and plant tissues.
- Assessment of treatment efficiency, including removal rates and stereoselective changes.
- Evaluation of micropollutant partitioning into sludge and uptake by Phragmites australis.
Main Results:
- 54 out of 88 monitored micropollutants were detected in treated wastewater, with removal efficiencies ranging from -112% to 98%.
- Stereo-selective removal was observed for chiral micropollutants like MDMA and atenolol.
- Micropollutants were found in sludge, with methylparaben, sertraline, fluoxetine, and desmethylcitalopram showing significant accumulation.
- While Phragmites australis showed uptake and metabolism of some recalcitrant compounds, this did not significantly contribute to overall removal at the studied hydraulic retention time.
Conclusions:
- Biodegradation is the dominant mechanism for micropollutant removal in HSSF constructed wetlands.
- Sludge partitioning and plant uptake contribute to micropollutant removal, but to a lesser extent than biodegradation.
- HSSF constructed wetlands demonstrate significant potential for removing a wide range of micropollutants from wastewater.
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