Stresses in non-equilibrium fluids: Exact formulation and coarse-grained theory
Matthias Krüger1, Alexandre Solon2, Vincent Démery3
1Max Planck Institute for Intelligent Systems, Heisenbergstr. 3, 70569 Stuttgart, Germany.
The Journal of Chemical Physics
|March 3, 2018
Summary
We derived an exact stress tensor for interacting Brownian particles and a generalized Landau-Ginzburg stress tensor. These tensors reveal how particle currents generate forces out of equilibrium, impacting Casimir forces and fluid dynamics.
Area of Science:
- Statistical Mechanics
- Soft Matter Physics
- Non-equilibrium Thermodynamics
Background:
- The stress tensor is crucial for understanding fluid dynamics and material properties.
- Existing models often struggle to accurately describe non-equilibrium systems with interacting particles.
Purpose of the Study:
- To formulate an exact stress tensor for interacting Brownian particles.
- To derive a generalized stress tensor for Landau-Ginzburg theory in non-equilibrium conditions.
- To investigate the relationship between stress tensor, external potentials, and particle currents.
Main Methods:
- Stochastic equations for density operators.
- Derivation of exact and Landau-Ginzburg stress tensors.
- Analysis of spatio-temporal correlations and Green-Kubo relations.
Main Results:
- The derived stress tensor for Brownian particles matches previous results.
- Particle currents induce additional forces in out-of-equilibrium systems.
- A general stress tensor form was established, applicable to various energy functionals.
- Spatial correlations of the stress tensor decay as power laws in driven confined systems.
Conclusions:
- The study provides a unified framework for stress tensors in equilibrium and non-equilibrium systems.
- The findings are relevant for understanding phenomena like classical Casimir forces.
- The research clarifies the role of stress tensor components in transport coefficients such as viscosity.
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