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Updated: Feb 13, 2026

Microcrystal Electron Diffraction of Small Molecules
Published on: March 15, 2021
Thermal expansion coefficient measurement from electron diffraction of amorphous films in a TEM
Misa Hayashida1, Kai Cui1, Marek Malac2
1Nanotechnology Research Center, 11421 Saskatchewan Drive, Edmonton T6G 2M9, Canada.
Abstract:
We measured the linear thermal expansion coefficients of amorphous 5-30 nm thick SiN and 17 nm thick Formvar/Carbon (F/C) films using electron diffraction in a transmission electron microscope. Positive thermal expansion coefficient (TEC) was observed in SiN but negative coefficients in the F/C films. In case of amorphous carbon (aC) films, we could not measure TEC because the diffraction radii required several hours to stabilize at a fixed temperature.
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