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Characterization of Full Set Material Constants and Their Temperature Dependence for Piezoelectric Materials Using Resonant Ultrasound Spectroscopy
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    Adding CuO to PMMnN-PZT ceramics lowers sintering temperatures for piezoelectric transformers (PTs). This enables high-power devices with excellent efficiency and power density using affordable Ag/Pd electrodes.

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    Area of Science:

    • Materials Science
    • Ceramic Engineering
    • Electrical Engineering

    Background:

    • Reliability of piezoelectric transformers (PTs) is crucial and depends heavily on fabrication quality.
    • Heterogeneity, prestress, and misalignment can negatively impact PT performance.

    Purpose of the Study:

    • Investigate unipoled multilayer PTs for high-power applications.
    • Optimize composition and co-firing profiles for low-temperature synthesis.
    • Achieve high efficiency and power density in fabricated PTs.

    Main Methods:

    • Addition of 0.2 wt% CuO to Pb$_{0.98}$Sr$_{0.02}$ (Mg$_{1/3}$Nb$_{2/3}$)$_{0.06}$(Mn$_{1/3}$Nb$_{2/3}$)$_{0.06}$(Zr$_{0.48}$Ti$_{0.52}$)$_{0.88}$O$_{3}$ (PMMnN-PZT).
    • Reduced co-firing temperature from 1240 °C to 930 °C.
    • Utilized Ag/Pd inner electrodes instead of Pt.

    Main Results:

    • CuO addition significantly lowered the co-firing temperature of PMMnN-PZT.
    • Low-temperature synthesized material exhibited excellent piezoelectric properties.
    • PTs co-fired at 930 °C with Ag/Pd showed performance comparable to those fired at 1240 °C with Pt.
    • Achieved 5-W output power, >90% efficiency, and 11.5 W/cm³ power density.

    Conclusions:

    • Low-temperature synthesis of high-quality PTs is feasible using CuO-modified PMMnN-PZT.
    • Reduced sintering temperatures allow for cost-effective electrode materials (Ag/Pd).
    • The developed PTs offer high performance suitable for demanding applications.