Functionalization of N-arylglycine esters: electrocatalytic access to C-C bonds mediated by n-Bu4NI
Mi-Hai Luo1, Yang-Ye Jiang1, Kun Xu1
1Beijing Key Laboratory of Environmental and Viral Oncology, College of Life Science & Bioengineering, Beijing University of Technology, Beijing 100124, China.
Abstract:
An efficient electrocatalytic functionalization of N-arylglycine esters is reported. The protocol proceeds in an undivided cell under constant current conditions employing the simple, cheap and readily available n-Bu4NI as the mediator. In addition, it is demonstrated that the mediated process is superior to the direct electrochemical functionalization.
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