Related Experiment Video
Updated: Feb 13, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Silyl-Phosphino-Carbene Complexes of Uranium(IV)
Erli Lu1, Josef T Boronski1, Matthew Gregson1
1School of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
Abstract:
Unprecedented silyl-phosphino-carbene complexes of uranium(IV) are presented, where before all covalent actinide-carbon double bonds were stabilised by phosphorus(V) substituents or restricted to matrix isolation experiments. Conversion of [U(BIPMTMS )(Cl)(μ-Cl)2 Li(THF)2 ] (1, BIPMTMS =C(PPh2 NSiMe3 )2 ) into [U(BIPMTMS )(Cl){CH(Ph)(SiMe3 )}] (2), and addition of [Li{CH(SiMe3 )(PPh2 )}(THF)]/Me2 NCH2 CH2 NMe2 (TMEDA) gave [U{C(SiMe3 )(PPh2 )}(BIPMTMS )(μ-Cl)Li(TMEDA)(μ-TMEDA)0.5 ]2 (3) by α-hydrogen abstraction. Addition of 2,2,2-cryptand or two equivalents of 4-N,N-dimethylaminopyridine (DMAP) to 3 gave [U{C(SiMe3 )(PPh2 )}(BIPMTMS )(Cl)][Li(2,2,2-cryptand)] (4) or [U{C(SiMe3 )(PPh2 )}(BIPMTMS )(DMAP)2 ] (5). The characterisation data for 3-5 suggest that whilst there is evidence for 3-centre P-C-U π-bonding character, the U=C double bond component is dominant in each case. These U=C bonds are the closest to a true uranium alkylidene yet outside of matrix isolation experiments.
Related Concept Videos
Electron Transport Chain: Complex III and IV
Protein Complex Assembly
Many viruses self-assemble into a fully functional unit using the infected host cell to...
Protein Complexes with Interchangeable Parts
The SCF ubiquitin ligase is a protein complex of five individual proteins. This complex attaches ubiquitin to other target proteins to mark them for degradation. In order...
Complex Numbers
Formation of Complex Ions
Pneumonia IV: Management
Bacterial Pneumonia Treatment
For bacterial pneumonia, antibiotics serve as the cornerstone of therapy. Initial treatment often begins with empirical antibiotics, tailored to the anticipated causative organism and adjusted based on culture results. Key antibiotic choices include:

