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Aggregation-induced emission of [3]cumulenes functionalized with heptagon-containing polyphenylenes
Vicente G Jiménez1, Rubén Tapia, Miguel A Medel
1Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Granada, E-18071 Granada, Spain. araceligc@ugr.es.
Abstract:
Turning on the fluorescence of [3]cumulenes: we report the luminescence at room temperature upon aggregation of [3]cumulenes functionalized with propeller-like heptagon-containing polyphenylenes. These endgroups turn on the emission of a [3]cumulene by steric protection and restriction of their intramolecular rotations in the aggregates.
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