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Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
Published on: May 27, 2020
Optical Selection Rule of Excitons in Gapped Chiral Fermion Systems
Xiaoou Zhang1, Wen-Yu Shan1, Di Xiao1
1Department of Physics, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, USA.
We discovered that the winding number (w), a topological property, dictates exciton optical selection rules in gapped chiral fermion systems. This finding enables electrical control over optical transitions in 2D materials.
Area of Science:
- Condensed Matter Physics
- Topological Materials
- 2D Materials
Background:
- Exciton optical selection rules govern light-matter interactions in solids.
- Topological properties of Bloch bands, like winding number, influence electronic and optical behavior.
- Chiral fermion systems and 2D materials offer unique platforms for exploring novel quantum phenomena.
Purpose of the Study:
- To establish the relationship between the winding number (w) and exciton optical selection rules in gapped chiral fermion systems.
- To propose novel material systems exhibiting tunable exciton properties.
- To demonstrate a pathway for electrical control of optical transitions in two-dimensional materials.
Main Methods:
- Theoretical analysis of exciton optical selection rules based on topological invariants (winding number).
- Investigation of C_{N}-invariant chiral fermion systems.
- Proposal and theoretical characterization of gapped surface states in topological crystalline insulators and biased 3R-stacked MoS_{2} bilayers.
Main Results:
- The winding number (w) directly governs the exciton optical selection rule in gapped chiral fermion systems.
- The angular momentum of bright exciton states is determined by w±1+nN, where n is an integer.
- Gapped surface states of topological crystalline insulators and biased MoS_{2} bilayers are proposed to host dark s-like excitons.
- Electrical gating can tune s-like excitons from bright to dark states by altering the winding number in MoS_{2} bilayers.
Conclusions:
- The winding number is a fundamental quantity controlling exciton optical transitions in gapped chiral fermion systems.
- Topological crystalline insulators and engineered 2D heterostructures like MoS_{2} bilayers are promising platforms for realizing tunable excitonic effects.
- This work provides a theoretical framework for the electrical control of optical properties in advanced materials.
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