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Updated: Feb 13, 2026

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
Published on: September 18, 2016
Nondirected Copper-Catalyzed Sulfoxidations of Benzylic C-H Bonds
Hao Yu1, Zhen Li1, Carsten Bolm1
1Institute of Organic Chemistry, RWTH Aachen University Landoltweg 1 , 52074 Aachen , Germany.
Abstract:
A copper-catalyzed sulfoxidation of benzylic C-H bonds by nondirected oxidative C(sp3)-H activation was developed. The process proceeds via sulfenate anions, which are generated by base-triggered elimination of β-sulfinyl esters and benzyl radicals. The functional group tolerance is high, and the product yields are good.
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