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Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
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Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
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Brick durability, strength, and appearance are crucial factors in construction, influencing the choice of bricks for specific applications. The process of freeze-thaw, for instance, significantly affects brick durability. This phenomenon occurs when water absorbed by a brick expands as it freezes, potentially causing damage when it melts and refreezes. Bricks are graded for durability: SW-grade bricks are the most durable, offering high strength and low water absorption, followed by MW-grade...
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Smooth, All-Solid, Low-Hysteresis, Omniphobic Surfaces with Enhanced Mechanical Durability.

Mathew Boban, Kevin Golovin, Brian Tobelmann

  • 1Rocket Propulsion Division , Air Force Research Laboratory , Edwards Air Force Base , California 93524 , United States.

ACS Applied Materials & Interfaces
|March 20, 2018
PubMed
Summary

Researchers developed a durable, smooth omniphobic coating that repels various liquids. This all-solid surface overcomes limitations of existing technologies, showing superior stability and resistance to mechanical abrasion for advanced applications.

Keywords:
durable coatingsfluorinatedliquid-repellentoleophobicomniphobic

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Area of Science:

  • Materials Science
  • Surface Chemistry

Background:

  • Omniphobic surfaces repel diverse liquids, offering benefits like self-cleaning and anti-fouling.
  • Current methods using texture or lubricants often lack long-term stability and durability.

Purpose of the Study:

  • To develop a robust, smooth omniphobic coating independent of substrate.
  • To overcome the limitations of existing omniphobic surface fabrication methods.

Main Methods:

  • Fabrication of an all-solid, smooth omniphobic coating using fluorinated polyurethane and fluorodecyl polyhedral oligomeric silsesquioxane.
  • Testing liquid droplet behavior (water, hexadecane, ethanol, silicone oil) on the coating.
  • Assessing surface durability through mechanical abrasion tests.

Main Results:

  • The novel coating demonstrated low-contact-angle hysteresis (<15°) for various liquids, enabling residue-free droplet sliding.
  • The all-solid, smooth surface exhibited superior retention of repellent properties compared to textured or lubricated surfaces after abrasion.
  • The coating proved substrate-independent.

Conclusions:

  • A new class of smooth, all-solid omniphobic coatings has been successfully fabricated.
  • These coatings offer enhanced durability and stability, overcoming key limitations of current technologies.
  • The developed material holds promise for applications requiring robust liquid repellency.