Related Experiment Video
Updated: Feb 12, 2026

Western Blotting Using the Invitrogen NuPage Novex Bis Tris MiniGels
Published on: August 22, 2007
Silver(i) complexes of bis- and tris-(pyrazolyl)azine derivatives - dimers, coordination polymers and a pentametallic
Izar Capel Berdiell1, Stuart L Warriner1, Malcolm A Halcrow1
1School of Chemistry, University of Leeds, Leeds, UK LS2 9JT. m.a.halcrow@leeds.ac.uk.
Abstract:
Silver(i) complexes of 2,4,6-tri(pyrazol-1-yl)pyridine (tpp), 2,4,6-tri(pyrazol-1-yl)pyrimidine (tpym), 2,4,6-tri(pyrazol-1-yl)-1,3,5-triazine (tpt) and 2,4-di(pyrazol-1-yl)-1,3,5-triazine (bpt) are reported. Dinuclear [Ag2(μ-tpp)2(MeCN)2][BF4]2·2MeCN and [Ag2(μ-tpym)2(MeCN)2][BF4]2 are formed from approximately planar [AgL(NCMe)]+ (L = tpp or bpym) centres, which dimerise via apical interactions to the pendant pyrazolyl donor on each ligand. Two polymeric solvatomorph phases [Ag2(μ-tpp)2][BF4]2·nMeNO2 were obtained by crystallising AgBF4 and tpp from nitromethane solution. One is composed of the same dimeric [Ag2(μ-tpp)2]2+ motif as the MeCN solvates, but with semibridging pyrazolyl substitutents replacing the solvent ligands. The other form has helicate [Ag2(μ-tpp)2]2+ dimers linked into chains by unsupported AgAg interactions. In contrast, [Ag5(μ3-tpym)4][BF4]5·2MeNO2 contains discrete pentametallic assemblies, of a flattened [Ag4(μ-tpym)4]4+ molecular square centred by the fifth silver ion. Three helical or linear 1D coordination polymer topologies are described for [Ag(μ-tpt)]X (X- = BF4- or ClO4-), where ditopic tpt ligands bind one silver ion in a [2 + 1] geometry and the other in bidentate, [1 + 1] or monodentate fashion. Finally, [Ag(bpt)]BF4 is a polymer of square planar silver ions linked by bis-bidentate bpt ligands. Most of the tpt and bpt structures include short anionπ contacts to the ligand triazinyl rings. Electrospray mass spectra confirm the oligomeric nature of the Ag/tpym and tpt complexes in MeNO2 solution.
Related Concept Videos
Protein Complex Assembly
Many viruses self-assemble into a fully functional unit using the infected host cell to...
Protein Complex Assembly
Coordination Compounds and Nomenclature
Assembly of Signaling Complexes
Interaction domains in cell signaling
Interaction domains recognize exposed features of their binding partners containing post-translationally modified sequences,...
Coordination Number and Geometry
Polymers

