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Updated: Feb 12, 2026

Optical Control of Living Cells Electrical Activity by Conjugated Polymers
Published on: January 28, 2016
Structural Information for Conjugated Polymers from Optical Modeling
Max Marcus1,2, Jonathan D Milward1,3, Anna Köhler4,5
1Department of Chemistry, Physical & Theoretical Chemistry Laboratory , University of Oxford , Oxford , OX1 3QZ , U.K.
Abstract:
We use a Frenkel-Holstein model of uncoupled chains in the adiabatic limit to simulate the optical spectra of the conjugated polymer ladder-type poly( p-phenylene) derivative (MeLPPP), which is a planar conjugated polymer with especially low interchain interactions. The theoretical calculations correctly reproduce the vibronic spectra and yield reasonable torsion angles between adjacent phenyl rings. The success of this approach indicates that, in contrast to interchain coupling, the strong electronic coupling along a polymer chain is more appropriately described in the adiabatic limit.
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