Mesoporous Hollow Sb/ZnS@C Core-Shell Heterostructures as Anodes for High-Performance Sodium-Ion Batteries

Combining the advantage of metal, metal sulfide, and carbon, mesoporous hollow core-shell Sb/ZnS@C hybrid heterostructures composed of Sb/ZnS inner core and carbon outer shell are rationally designed based on a robust template of ZnS nanosphere, as anodes for high-performance sodium-ion batteries (SIBs). A partial cation exchange reaction based on the solubility difference between Sb₂ S₃ and ZnS can transform mesoporous ZnS to Sb₂ S₃ /ZnS heterostructure. To get a stable structure, a thin contiguous resorcinol-formaldehyde (RF) layer is introduced on the surface of Sb₂ S₃ /ZnS heterostructure. The effectively protective carbon layer from RF can be designed as the reducing agent to convert Sb₂ S₃ to metallic Sb to obtain core-shell Sb/ZnS@C hybrid heterostructures. Simultaneously, the carbon outer shell is beneficial to the charge transfer kinetics, and can maintain the structure stability during the repeated sodiation/desodiation process. Owing to its unique stable architecture and synergistic effects between the components, the core-shell porous Sb/ZnS@C hybrid heterostructure SIB anode shows a high reversible capacity, good rate capability, and excellent cycling stability by turning the optimized voltage range. This novel strategy to prepare carbon-layer-protected metal/metal sulfide core-shell heterostructure can be further extended to design other novel nanostructured systems for high-performance energy storage devices.