Enhanced upconversion in one-dimensional photonic crystals: a simulation-based assessment within realistic material...

This paper presents a simulation-based assessment of the potential for improving the upconversion efficiency of β-NaYF₄:Er³⁺ by embedding the upconverter in a one-dimensional photonic crystal. The considered family of structures consists of alternating quarter-wave layers of the upconverter material and a spacer material with a higher refractive index. The two photonic effects of the structures, a modified local energy density and a modified local density of optical states, are considered within a rate-equation-modeling framework, which describes the internal dynamics of the upconversion process. Optimal designs are identified, while taking into account production tolerances via Monte Carlo simulations. To determine the maximum upconversion efficiency across all realistically attainable structures, the refractive index of the spacer material is varied within the range of existing materials. Assuming a production tolerance of σ = 1 nm, the optimized structures enable more than 300-fold upconversion photoluminescence enhancements under one sun and upconversion quantum yields exceeding 15% under 30 suns concentration.