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Nonlinear Variation in the Composition and Optical Band Gap of an Alloyed Cluster-Based Open-Framework Metal
Jian Lin1, Dandan Hu1, Huajun Yang1
1College of Chemistry, Chemical Engineering and Materials Science , Soochow University , Jiangsu 215123 , China.
Abstract:
Unexpected nonlinear variation in the composition and optical band gap was observed in an alloyed open-framework metal chalcogenide composed of supertetrahedral clusters. A tentative hypothesis was proposed to explain how the title compound [In28Se54(H2O)4]·24H+-PR· nH2O (PR = piperidine) exhibits a limitation in the S-alloying level and a large variation in the optical band gap.
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