A microbial electro-fenton cell for removing carbamazepine in wastewater with electricity output
Wei Wang1, Yaobin Lu1, Haiping Luo1
1Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology, School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou, 510275, China.
Abstract:
High electrical energy is required for the electro-Fenton process to remove pharmaceuticals and personal care products (PPCPs) in wastewater. The aim of this study was to develop a novel and more cost-effective process, specifically a microbial electro-Fenton cell (MeFC), for treating PPCPs in wastewater. Acetylene black was selected as the catalyst for H2O2 electrogeneration and Fe-Mn binary oxide for hydroxyl radical production. In addition to lowering energy needs, the MeFC produced a maximum power density of 112 ± 11 mW/m2 with 1 g/L acetate as a representative substrate and 10 mg/L carbamazepine (CBZ) as a typical PPCP. Comparing with electro-Fenton process, the CBZ removal in the MeFC was 38% higher within 24 h operation (90% vs. 62%). Furthermore, the CBZ removal rate in the MeFC was 10-100 times faster than that in other biological treatment processes. Such enhanced degradation of CBZ in the MeFC was attributed to the synergistic reactions between radical oxidation of CBZ and biodegradation of degradative intermediates. The MeFC provides a promising method to remove PPCPs from wastewater coupling with efficient removal of other biodegradable organics.
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