Chemical profiling of PM₁₀ from urban road dust

Road dust resuspension is one of the main sources of particulate matter with impacts on air quality, health and climate. With the aim of characterising the thoracic fraction, a portable resuspension chamber was used to collect road dust from five main roads in Oporto and an urban tunnel in Braga, north of Portugal. The PM₁₀ samples were analysed for: i) carbonates by acidification and quantification of the evolved CO₂, ii) carbonaceous content (OC and EC) by a thermo-optical technique, iii) elemental composition by ICP-MS and ICP-AES after acid digestion, and iv) organic speciation by GC-MS. Dust loadings of 0.48±0.39mgPM₁₀m^-2 were obtained for asphalt paved roads. A much higher mean value was achieved in a cobbled pavement (50mgPM₁₀m^-2). In general, carbonates were not detected in PM₁₀. OC and EC accounted for PM₁₀ mass fractions up to 11% and 5%, respectively. Metal oxides accounted for 29±7.5% of the PM₁₀ mass from the asphalt paved roads and 73% in samples from the cobbled street. Crustal and anthropogenic elements, associated with tyre and brake wear, dominated the inorganic fraction. PM₁₀ comprised hundreds of organic constituents, including hopanoids, n-alkanes and other aliphatics, polycyclic aromatic hydrocarbons (PAH), alcohols, sterols, various types of acids, glycerol derivatives, lactones, sugars and derivatives, phenolic compounds and plasticizers. In samples from the cobbled street, these organic classes represented only 439μgg^-1PM₁₀, while for other pavements mass fractions up to 65mgg^-1PM₁₀ were obtained. Except for the cobbled street, on average, about 40% of the analysed organic fraction was composed of plasticizers. Although the risk via inhalation of PAH was found to be insignificant, the PM₁₀ from some roads can contribute to an estimated excess of 332 to 2183 per million new cancer cases in adults exposed via ingestion and dermal contact.