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Updated: Feb 12, 2026

Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
Published on: December 20, 2016
Relevance of ion clusters for Li transport at elevated salt concentrations in [Pyr12O1][FTFSI] ionic liquid-based
Marc Brinkkötter1, Guinevere A Giffin, Arianna Moretti
1Institute of Physical Chemistry, University of Muenster, Corrensstraße 28/30, 48149 Münster, Germany. schoenho@uni-muenster.de.
Abstract:
In binary ionic liquid/Li salt mixtures with the novel asymmetric anion FTFSI, electrophoretic mobility μi values of all ion species were determined using electrophoretic NMR. Li was determined to migrate in negatively charged Li-anion clusters towards the anode. This vehicular transport mechanism was shown to have decreasing relevance at elevated salt concentrations.
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