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Updated: Feb 12, 2026

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
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CuBi2O4 Prepared by the Polymerized Complex Method for Gas-Sensing Applications.

Yun-Hyuk Choi1, Dai-Hong Kim2, Seong-Hyeon Hong2

  • 1Department of Chemistry , Texas A&M University , College Station , Texas 77842-3012 , United States.

ACS Applied Materials & Interfaces
|April 12, 2018
PubMed
Summary
This summary is machine-generated.

The gas-sensing properties of copper bismuth oxide (CuBi2O4) were investigated for the first time. Higher defect concentrations, controlled by calcination temperature, significantly enhance gas sensor responses, particularly for ethanol.

Keywords:
CuBi2O4chemical defectgas sensorp-typepolymerized complex method

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Area of Science:

  • Materials Science
  • Solid-State Chemistry
  • Chemical Sensing

Background:

  • Multicomponent oxides offer versatile alternatives to binary oxides for gas sensing applications.
  • Controlling intrinsic defects is crucial for tailoring the performance of metal oxide gas sensors.

Purpose of the Study:

  • To investigate the gas-sensing properties of CuBi2O4 towards various reducing and oxidizing gases.
  • To explore the influence of calcination temperature on the defect chemistry and sensing performance of CuBi2O4.
  • To establish the relationship between defect concentration and gas-sensing characteristics in multicomponent oxides.

Main Methods:

  • Synthesis of single-phase polycrystalline CuBi2O4 using the polymerized complex method (Pechini method).
  • Modulation of defect, optical, and electronic properties by varying calcination temperatures (500-700 °C).
  • Gas-sensing measurements toward ethanol, ammonia, hydrogen, carbon monoxide, hydrogen sulfide, and nitrogen dioxide.

Main Results:

  • CuBi2O4 calcined at 500 °C exhibited high concentrations of Cu+-oxygen vacancy defect complexes, leading to enhanced gas responses.
  • The sensor demonstrated a high response (10.4) to 1000 ppm ethanol at 400 °C.
  • Gas-sensing behavior was found to be strongly influenced by intrinsic defect concentration, which is controllable via calcination temperature.

Conclusions:

  • Intrinsic defect concentration is a key factor governing the gas-sensing characteristics of CuBi2O4.
  • Calcination temperature is an effective parameter for tuning defect chemistry and optimizing sensor performance.
  • This study provides insights into the effect of chemical defects on gas sensing in multicomponent oxides.