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Hypervalent Iodine Reagents by Anodic Oxidation: A Powerful Green Synthesis
Mohamed Elsherbini1, Thomas Wirth1
1School of Chemistry, Cardiff University, Park Place, Main Building, Cardiff, CF10 3AT, UK.
Abstract:
The anodic oxidation of aryl iodides is a powerful method for the synthesis of hypervalent iodine reagents, which eliminates the necessity to use expensive or hazardous chemical oxidizing reagents. The hypervalent iodine reagents generated at the anode are successfully used as either in-cell or ex-cell mediators for different valuable chemical transformations such as fluorinations and oxidative cyclizations. More recently, recyclable mediators and catalytic protocols have been developed.
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