Related Experiment Video
Updated: Feb 11, 2026

Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions
Published on: July 28, 2022
Correction: Copper-mediated regioselective C-H etherification of naphthylamides with arylboronic acids using water as
Subhasish Roy1, Sourav Pradhan, Tharmalingam Punniyamurthy
1Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, India. tpunni@iitg.ernet.in.
Abstract:
Correction for 'Copper-mediated regioselective C-H etherification of naphthylamides with arylboronic acids using water as an oxygen source' by Subhasish Roy et al., Chem. Commun., 2018, DOI: 10.1039/c8cc02158a.
Related Concept Videos
Regioselectivity and Stereochemistry of Acid-Catalyzed Hydration
Water: A Bronsted-Lowry Acid and Base
Regioselectivity of Electrophilic Additions-Peroxide Effect
Distance Corrections
Power Factor Correction
Regioselectivity and Stereochemistry of Hydroboration
Hydroboration proceeds in a concerted fashion with the attack of borane on the π bond, giving a cyclic four-centered transition state. The –BH2 group is bonded to the less substituted carbon and –H to the more substituted carbon. The concerted nature requires the simultaneous addition of –H and –BH2 across the same face of the alkene giving syn stereochemistry.

