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Updated: Feb 11, 2026

Anionic Polymerization of an Amphiphilic Copolymer for Preparation of Block Copolymer Micelles Stabilized by π-π Stacking Interactions
Published on: October 10, 2016
Ion-Pairing Assemblies of π-Electronic Anions Formed by Intramolecular Hydrogen Bonding
Hiromitsu Maeda1, Yuka Takeda1, Yohei Haketa1
1Department of Applied Chemistry, College of Life Sciences, Ritsumeikan University, Kusatsu, 525-8577, Japan.
Abstract:
π-Extended nitro-substituted dipyrrolylphenol derivatives were synthesized, and upon deprotonation they provided π-electronic anions stabilized by hydrogen bonding between the phenolate (phenoxide) moiety and the pyrrole NH group. Ion-pairing assemblies of the deprotonated anions were formed in the solid state and as mesophases. In the solid state, the extended π plane was found to be more suitable to form charge-by-charge assemblies in combination with tetraalkylammonium cations with highly anisotropic orientations as a result of efficient stacking. The mesophase also included a charge-by-charge assembly comprising the deprotonated anion bearing aliphatic chains, as revealed by synchrotron X-ray diffraction analysis.
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