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Updated: Feb 11, 2026

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
Published on: February 10, 2023
Straightforward Synthesis of Single-Crystalline and Redox-Active Cr(II)-carboxylate MOFs
Michał K Leszczyński1, Arkadiusz Kornowicz2, Daniel Prochowicz1
1Institute of Physical Chemistry Polish Academy of Sciences Kasprzaka 44/52 , 01-224 Warsaw , Poland.
Abstract:
We report on a facile and environmentally friendly synthetic approach for single-crystalline chromium(II) carboxylate metal-organic frameworks (i.e., Cr3(BTC)2·3H2O (1) and Cr(hfipbb)·H2O (2) at room temperature in water. Both MOFs can be easily dehydrated, affording single-crystalline materials with open Cr(II) sites. In addition, the redox activity and porosity of the resulting Cr(II) MOFs were examined.
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