Related Experiment Video
Updated: Feb 11, 2026

Robotic Cochlear Implantation for Direct Cochlear Access
Published on: June 16, 2022
Direct access to a cAAC-supported dihydrodiborene and its dianion
Merle Arrowsmith1, James D Mattock, Julian Böhnke
1Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. h.braunschweig@uni-wuerzburg.de.
Abstract:
The two-fold reduction of (cAAC)BHX2 (cAAC = 1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidin-2-ylidene; X = Cl, Br) provides a facile, high-yielding route to the dihydrodiborene (cAAC)2B2H2. The (chloro)hydroboryl anion reduction intermediate was successfully isolated using a crown ether. Overreduction of the diborene to its dianion [(cAAC)2B2H2]2- causes a decrease in the B-B bond order whereas the B-C bond orders increase.
More Related Videos
09:45Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
Published on: March 20, 2017
06:10Preparation of Sample Support Films in Transmission Electron Microscopy using a Support Floatation Block
Published on: April 8, 2021
Related Concept Videos
Self-Help Support Groups
Accessibility and Cost-Effectiveness
One of the primary strengths of self-help...
Support Reactions
The purpose of the supports is to prevent the translational motion of the system by applying an equal and opposite force and to prevent the system's rotation by applying...
Support Reactions in Three Dimensions
Ball and Socket Joint is one of the supports allowing free rotation about any axis. This freedom of rotation is...
Directing Effect of Substituents: meta-Directing Groups
Bone as Supporting Connective Tissue
Bone Matrix
Bone, or osseous tissue, is a connective tissue that has a large amount of two different types of matrix material. The organic matrix is similar to the matrix material found in other connective tissues, including some amount of collagen and elastic fibers. This gives strength and flexibility to the tissue. The inorganic matrix consists of mineral salts— mostly calcium salts—...
Directing Effect of Substituents: ortho–para-Directing Groups