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2D Metal Chalcogenides Incorporated into Carbon and their Assembly for Energy Storage Applications
Zongnan Deng1, Hao Jiang1, Chunzhong Li1
1Key Laboratory for Ultrafine Materials of Ministry of Education & School of Materials Science and Engineering, East China University of Science & Technology, P. O. Box 258, 130 Meilong Rd., Shanghai, 200237, China.
Abstract:
2D metal chalcogenides have become a popular focus in the energy storage field because of their unique properties caused by their single-atom thicknesses. However, their high surface energy and van der Waals attraction easily cause serious stacking and restacking, leading to the generation of more inaccessible active sites with rapid capacity fading. The hybridization of 2D metal chalcogenides with highly conductive materials, particularly, incorporating ultrasmall and few-layered metal chalcogenides into carbon frameworks, can not only maximize the exposure of active sites but also effectively avoid their stacking and aggregation during the electrochemical reaction process. Therefore, a satisfactory specific capacity will be achieved with a long cycle life. In this Concept, the representative progress on such intriguing nanohybrids and their applications in energy storage devices are mainly summarized. Finally, an outlook of the future development and challenges of such nanohybrids for achieving an excellent energy storage capability is also provided.
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