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Synthesis and Functionalization of 3D Nano-graphene Materials: Graphene Aerogels and Graphene Macro Assemblies
Published on: November 5, 2015
Assembly of DNA/Fullerene Hybrid Materials
Alan M Cassell1, Walter A Scrivens1, James M Tour1
1Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208 (USA), Fax: (+1) 803-777-9521.
Abstract:
Ordering of cationic fullerene derivatives on a DNA template by phosphate/fullerene complexation provides a rapid route to organic materials several hundred nanometers in length (shown on the right). Hydrophobic interactions between the fullerene units lead to DNA supercoiling that can be relieved by adding a nonionic surfactant. The products are easily imaged by transmission electron microscopy without the need for heavy-metal staining.
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