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Updated: Feb 11, 2026

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
Published on: April 9, 2018
Synthesis and Crystal Structure of δ-GeS2 , the First Germanium Sulfide with an Expanded Framework Structure
Mark J MacLachlan1, Srebri Petrov1, Robert L Bedard2
1Lash Miller Chemical Laboratories, University of Toronto, 80 St. George Street, Toronto, M5S 3H6 (Canada), Fax: (+1) 416-971-2011.
Abstract:
Polycondensation of molecular adamantanoid [Ge4 S10 ]4- precursors at a remarkably low temperature (50°C) affords the crystalline binary dichalcogenide δ-GeS2 . Its crystal structure contains two interpenetrating cristobalite-like frameworks composed of adamantanoid [Ge4 S6 S4/2 ] building blocks. Rings containing 24 atoms form the largest pores of each network (shown on the right).
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