Metal--Metal "Communication" of Rh or Pd with Nd in Novel Heterobinuclear Complexes

Anke Spannenberg¹, Markus Oberthür¹, Henrik Noss¹

¹Abt. Komplexkatalyse, Institut für Organische Katalyseforschung an der Universität, Buchbinderstrasse 5-6, D-18055 Rostock (Germany), Fax: (+49) 381-466-9374.

Angewandte Chemie (International Ed. in English)

|May 2, 2018

Abstract:

The reaction of a neodymium "ate" complex and an electron-rich transition metal chloride by salt elimination is an efficient method for synthesizing heterobinuclear compounds which contain a lanthanide and a Group 9 or 10 metal [Eq. (1), H₂ Ap=2-amino-4-methylpyridine]. The use of bisaminopyridinato ligands allows extremely short distances between Rh or Pd and Nd.

Keywords:

Lanthanides Metal-metal interactions N ligands Palladium Rhodium

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