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[Te6 N8 (TeCl4 )4 ]-Tellurium Nitride Stabilized by Tellurium Tetrachloride
Werner Massa1, Carsten Lau1, Michael Möhlen1
1Fachbereich Chemie der Universität, Hans-Meerwein-Strasse, D-35032 Marburg (Germany), Fax: (+49) 6421-28-8917.
Abstract:
Shielding by four TeCl4 molecules is observed for the distorted rhombic dodecahedron core of the tellurium nitride Te6 N8 (see picture). With the characterization of this structure, the composition of the tellurium nitride discovered 100 years ago has now been determined. As a result of the shielding effect, the explosive character of the nitride is lost.
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