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Synthesis and Properties of Lanthanum- Pyrene Complexes-Structure of [(Cp*La)3 (μ-Cl)3 (thf)(μ-η2 :η6 :η6 -C16 H10
Karl-Heinz Thiele1, Sergio Bambirra1, Joachim Sieler2
1Institut für Anorganische Chemie der Universität Halle-Wittenberg, Kurt-Mothes-Strasse 2, D-06120 Halle (Germany), Fax: (+49) 345-55-27028.
Abstract:
Different bonding modes are characteristic for the lanthanum centers of the title compound, a trinuclear lanthanum-pyrene complex in which an arene trianion is present for the first time (see picture for the structure). Thus, La1 and La3 reside in a tetrahedral environment, the La2 center in a distorted trigonal-bipyramidal one.
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