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[Bi2 (O2 CCF3 )4 ]⋅C6 Me6 -Arene Adduct of a Reduced Main Group Element Carboxylate with Paddle Wheel Structure
Walter Frank1, Vera Reiland1, Guido J Reiß1
1Fachbereich Chemie der Universität, Postfach 3049, D-67653 Kaiserslautern (Germany), Fax: (+49) 631 -205-2187.
Abstract:
The first main group dimetal complex with tetragonal-prismatic coordination is [Bi2 (O2 CCF3 )4 ] (structure depicted), which forms a component of a linear one-dimensional coordination copolymer with hexamethylbenzene molecules. The "paddle wheel" motif well-known from chromium(II) acetate and hundreds of other transition metal complexes is thus introduced into the coordination chemistry of main group elements.
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