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Neutron Diffraction Study of [Nd(AlMe4 )3 ]⋅0.5 Al2 Me6 at 100 K: The First Detailed Look at a Bridging Methyl Group
Wim T Klooster1, Roy S Lu2, Reiner Anwander3
1Chemistry Department, Brookhaven National Laboratory" Upton, NY 11973, (USA).
Abstract:
Weak agostic Nd⋅⋅⋅H interactions and Nd-C bonds are involved in the bonding of the bridging methyl groups in the title compound (see sketch on the right): Two of the three H atoms of the methyl group are directed at the Nd center. The C atoms have distorted trigonal-bipyramidal geometry with the Nd atom and one of the H atoms (HA ) as axial ligands, and the Al atom and the other two H atoms (HB and HC ) in equatorial positions. The Al2 Me6 "solvate" molecule is disordered.
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