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Ca5 Cl3 (C2 )(CBC): A Compound with a Layer Structure and an Unusual Anion Combination
Olaf Reckeweg1, Hans-Jürgen Meyer1
1Institut für Anorganische Chemie der Universität, Auf der Morgenstelle 18, D-72076 Tübingen (Germany), Fax: (+49) 7071-295702.
Abstract:
Allene homologous cumulenes are not always linear! The title compound, which has now been synthesized and structurally characterized, contains a BC2 unit that is isoelectronic with CO2 and that deviates by 16° from linearity without losing the double-bond character of the B-C bonds. The BC2 unit is located in the center of a bicapped trigonal prism of calcium ions (see picture).
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