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Updated: Feb 11, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Unique Formation of a Crystal Phase Containing Cyclic Oligomers and Helical Polymers of the Same Monomeric Fragment
Norberto Masciocchi1, G Attilio Ardizzoia2, Girolamo LaMonica2
1Dipartimento di Chimica Strutturale e Stereochimica Inorganica, Università di Milano, via Venezian 21, I-20133 Milano (Italy), Fax: (+39) 02-7063-5288.
Abstract:
The yellow, microcrystalline compound [Cu(pymo)] (Hpymo=2-hydroxypyrimidine) has been characterized with the newly emerging technique of ab initio X-ray powder diffraction. A unique and unprecedented crystal phase containing cyclic oligomers and infinite helical polymers (see picture) of the same monomeric fragment is selectively formed upon reaction of [Cu(CH3 CN)4 ][BF4 ] and Hpymo with NEt3 .
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