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Updated: Feb 11, 2026

Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain
Published on: March 27, 2018
Synthesis of Symmetric Metallocenes from Metallic Calcium, Strontium, or Barium and Pentaisopropylcyclopentadienyl
Helmut Sitzmann1, Thomas Dezember1, Michael Ruck2
1FB Chemie der Universität, Erwin-Schrödinger-Strasse, D-67663 Kaiserslautern (Germany), Fax: (+49) 631-205-2187, http://www.uni-kl.de/FB-Chemie/Sitzmann/index.html.
Abstract:
The largest interplanar distance known to date between adjacent parallel rings of any sandwich compound (5.497(3) Å) is displayed by decaisopropylbarocene, the first heavy alkaline earth metal sandwich compound to possess axial symmetry. A new efficient metallocene formation [Eq. (1)] utilizes the free cyclopentadienyl radical [C5 R5 ]. (R=CHMe2 ) as an oxidizing agent for elemental Ca, Sr, and Ba (M).
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