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Updated: Feb 11, 2026
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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
Acrylate-Assisted Arene-Chromium Bond Cleavage: Generation of a [Cr(CO)2 ] Fragment under Mild Conditions
E Peter Kündig1, Mikhail Kondratenko1, Patrick Romanens1
1Département de Chimie Organique, Université de Genève, 30 Quai Ernest Ansermet, CH-1211 Genève 4 (Switzerland), Fax: (+41) 22-328-7396.
Abstract:
Displacement of the benzene ligand in 1 surprisingly occurs more readily than that of the methyl acrylate ligand. This paves the way for 1 to undergo arene exchange and arene substitution reactions, which may be triggered by a η2 →η4 haptotropic rearrangement of the acrylate. Complex 1 is thus a mild precursor of the highly unsaturated fragments [Cr(CO)2 ] (see scheme) and [Cr(CO)2 (η2 -acrylate)].
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