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Updated: Feb 11, 2026

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Multiple Ga-Ga Bonding Character in Na2 [Ga(GaTrip2 )3 ], and a Comparison with Neutral Ga(GaTrip2 )3
Rudolf J Wehmschulte1, Philip P Power1
1Department of Chemistry, University of California, Davis, CA 95616 (USA), Fax: (+1) 530-752-8995.
Abstract:
Delocalized over the Ga4 framework, the two electrons are lost in the oxidation of Na2 [Ga(GaTrip2 )3 ] to Ga(GaTrip2 )3 . This leads to a lengthening of the Ga-Ga bond by about 0.08 Å. Ar=Trip=2,4,6-iPr3 C6 H2 .
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