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The Stability of the Oxidation State +4 in Group 14 Compounds from Carbon to Element 114
Michael Seth1, Knut Faegri2, Peter Schwerdtfeger1
1Department of Chemistry, University of Auckland, Private Bag 92019, Auckland (New Zealand), Fax: (+64) 9-3737422.
Abstract:
The stability of the oxidation state +4 decreases from silicon to element 114, as shown by relativistic and nonrelativistic calculations on the hydrides, fluorides, and chlorides of the Group 14 elements (the energies of the decomposition reaction (1) are given in the plot). Thus it is unlikely that superheavy element 114, which may have stable isotopes due to its magic numbers of protons and neutrons, can be studied by atom-at-a-time chemistry in the oxidation state +4.
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