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The First Heterotriquinone and Dicyanoheterotriquinone Methide That Undergo a Five-Stage Amphoteric Redox Reaction
Kazuko Takahashi1, Satoshi Fujita1, Kimio Akiyama2
1Department of Chemistry, Graduate School of Science Tohoku University, Sendai 980-8578 (Japan), Fax: (+81) 22-217-6560.
Abstract:
The dicyanomethylene group and not the quinone oxygen atoms is the site of the first one-electron reduction for the dicyanohetereotriquinone methide 1, although the dicyanomethylene group is substituted at a cyclopentadienyl-like five-membered ring! Compound 1 is amphoteric and undergoes a five-stage sequence of one-electron redox reactions.
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