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Updated: Feb 11, 2026

Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
Published on: May 28, 2014
Yttrate-Mediated Ligand Transfer and Direct Synthesis as a Route to Amidopalladium Complexes
Anke Spannenberg1, Perdita Arndt1, Rhett Kempe1
1Abt. Komplexkatalyse, IfOK an der Universität Rostock, Buchbinderstrasse 5-6, D-18055 Rostock (Germany), Fax: (+49) 381-466-9374.
Abstract:
A ligand transfer from yttrium to palladium and the regeneration of 1 are the crucial steps in the efficient synthesis of the very strained amidopallium complex 2 from [(cod)PdCl2 ] and 1 (cod=cyclooctadiene). In the light of the numerous "ate" complexes of early transition metals, this synthetic route should have enormous potential.
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