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Published on: September 23, 2018
A Silatetragallane-Classical Heterobicyclopentane or closo-Polyhedron?
Gerald Linti1, Wolfgang Köstler1, Holger Piotrowski1
1Institut für Anorganische Chemie der Universität, Engesserstrasse, Geb. 30.45, D-76128 Karlsruhe (Germany), Fax: (+49) 721-608-4854.
Abstract:
Classical and nonclassical can be used to describe the bonding in the polyhedral Ga4 Si framework of the silagallanate ion [Me3 SiSi{GaSi(SiMe3 )3 }3 GaSiMe3 ]- (the GaSi framework is depicted in the picture). This is the result of density functional calculations that were carried out on model compounds. The cluster was obtained by ultrasonication of gallium and iodine and subsequent reaction with (Me3 Si)3 Li(thf)3 .
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