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Selective Activation of Ar-Cl and Ar-C Bonds with Iron(II) Complexes
Géraldine Poignant1, Sourisak Sinbandhit2, Loïc Toupet3
1UMR 6509 CNRS-Université de Rennes 1, "Organométalliques et Catalyse: Chimie et Electrochimie Moléculaires", Beaulieu, Université de Rennes 1, F-35042 Rennes Cedex (France), Fax: (+33) 299-281646.
Abstract:
The electrophilic iron-carbene chelate complexes 1 and 2 react with alkoxides RO- to give the neutral chelate complex 3 and the carbene complex 4, respectively. Depending on the nature of the chelating ortho substituent, selective activation of the Ar-Cl or Ar-C bond occurs; these processes are promoted by the chelation.
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