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The Azide-Nitrilimine Analogy in Aluminum Chemistry
Norbert Emig1, François P Gabbaï2, Harald Krautscheid3
1Laboratoire de Chimie de Coordination du CNRS, 205, route de Narbonne, 31077 Toulouse Cédex (France), Fax: (+33) 561 55 30 03.
Abstract:
Tetracoordinate aluminum derivatives featuring an AlNNCR fragment are stable and possess a rich structural diversity, as exemplified by the nitrilimines 1 and 2, similar to that observed for the related azides. Compound 1 is the first structurally characterized six-membered AlN heterocycle in which the nitrogen and aluminum centers exhibit different coordination numbers. R=P(NiPr2 )2 ; R'=iBu; E=N, CR.
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