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Trihydroxycarbenium Hexafluorometalates: Salts of Protonated Carbonic Acid
Rolf Minkwitz1, Stefan Schneider1
1Fachbereich Chemie der Universität, D-44221 Dortmund (Germany), Fax: (+49) 231-755-3797.
Abstract:
Stabilization by salt formation: carbonic acid, which is not available as a pure substance, was isolated in the form of its trihydroxycarbenium salts, C(OH)3+ MF6- (M=As, Sb), from the reaction of carbonic acid bis(trimethylsilyl) ester in the superacids HF/MF5 . The structure of the cation is shown in the picture. The ion was also characterized by vibrational spectroscopic studies.
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